Welcome to the home page of the Blakemore Group! We are a research group in the Department of Chemistry at the University of Kansas.

Our aim is to improve the sustainable production of chemicals, fuels, and energy using the tools of inorganic and organometallic chemistry, molecular electrochemistry, and surface chemistry. Our active projects are diverse in scope and span a number of topics:

Molecular catalysis and metal-ligand cooperation. We are investigating the reactivity and catalytic properties of half-sandwich metal complexes, and are specifically focused on understanding the interconversion of [Cp*] and [Cp*H] ligands as a route to development of new catalysts.

Coordination chemistry of multimetallic complexes. We are synthesizing and characterizing heterobimetallic complexes, in order to understand their properties and rationally design improved complexes for new applications. Our specific focus is on understanding how two closely spaced metals impact each others' properties.

Applications of the electrochemical quartz crystal microbalance. We are using the EQCM to probe the formation and reactivity properties of metallic solids during reductive molecular electrocatalysis, a challenge that impacts understanding of mechanism and electrocatalyst function in energy research.

Structure-function studies of chemically modified electrodes. We are studying the immobilization of metal complexes on electrodes in order to understand the role of molecular structure in their behavior and stability. Our goal is to rationally design systems for applications in areas like separations science.

New media for carbon dioxide conversion. In collaboration with Profs. Kevin Leonard and Bala Subramaniam at the KU Center for Environmentally Beneficial Catalysis, we are developing new media for carbon dioxide conversion to more useful chemicals.

Photoinduced reactivity. In collaboration with Prof. Chris Elles, our group is designing new metal complexes for studies of light-induced reactivity, in order to build up a platform of compounds for use in photodynamic therapy.

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We need the kind of courage that can withstand the subtle corruption of the cynics, so that 
we can show the world that we are not afraid of the future.
It has always been easy to hate and destroy, but to build and to cherish is [the real challenge].
–Elizabeth R.

 

Recent News

1 July 2019 – Congratulations to our former postdoc Dr. Davide Lionetti, who has started his independent career as a tenure-track Assistant Professor in the Department of Chemistry at Franklin & Marshall College in Lancaster, Pennsylvania! F&M, founded in 1787, is a prestigious liberal arts college that is among the oldest institutions of higher education in the US. We thank Davide for his foundational leadership of our group, and wish him all the best for new endeavors!!!

24 June 2019 – Our collaborative research with the Artificial Photosynthesis Group at Brookhaven National Laboratory is underway! Yun (G4) is spending the summer at the lab, in order to collect kinetic data on the mechanism of H2 production by our half-sandwich rhodium complexes. Exciting techniques available at BNL include pulse radiolysis and stopped-flow methods. Thanks to our hosts Etsuko Fujita, Dmitry Polyansky, and David Grills for the opportunity to work together!

9 April 2019 – Congratulations to our undergraduate researchers Emily Boyd and Shaun Kelsey, who have been named recipients of US NSF Graduate Research Fellowships! The NSF GRF is among the most prestigious fellowships in the US, and provides full support for three years of graduate study. Way to go!

Funding Sources

Our work is supported by the US Department of Energy, US National Science Foundation, KU Hall Chemical Research Fund, and the Spring Creek Fund.